Pigment Red 48:2 (HP RED 23124J) – Calcium Lake Red | Honor Pigments
Pigment Red 48:2 (HP RED 23124J) calcium-lake monoazo red: bluish-ruby shade, 260°C heat resistance, Blue Scale 4-5 for gravure inks and plastics.
Pigment Red 48:2 (HP RED 23124J) — Calcium-Lake Monoazo Red for Gravure Ink, Packaging Ink, and Plastics
A calcium-lake BONA monoazo red (C.I. 15865:2) delivering bluish-ruby shade, 260°C heat resistance and Blue Scale 4-5 lightfastness for gravure packaging inks and polyolefin coloring.
Product Overview
Pigment Red 48:2 (HP RED 23124J) is the calcium salt of a BONA (β-oxynaphthoic acid) monoazo red, C.I. 15865:2, produced by diazotizing 2B acid and coupling onto 2,3-acid, then laking with calcium. In 1986 the Gravure Technical Association (GTA) in the USA adopted PR48:2 as its standard process red for gravure packaging inks, making this one of the most widely specified red pigments in packaging printing.
The calcium lake yields bluish-red shades referred to as ruby — substantially bluer than PR48:1 and noticeably yellower than PR57:1. The HP RED 23124 TDS lists heat resistance of 260°C, and 1/3 SD HDPE colorations with 1% TiO2 are heat stable to 230°C for 5 minutes (Industrial Organic Pigments, 3rd ed.). Lightfastness reaches Blue Scale step 4-5 in 1/1 SD letterpress proofs, two to three steps above PR48:1. These properties position the pigment for gravure and packaging inks, polyolefin coloring, and industrial paints.
Key Benefits
Bluish-Ruby Shade for Process Red
PR48:2 was adopted by the Gravure Technical Association as the standard process red for gravure packaging inks in 1986. Its ruby tone is substantially bluer than PR48:1 and noticeably yellower than PR57:1.
260°C Heat Resistance (TDS)
The HP RED 23124 TDS lists heat resistance of 260°C. 1/3 SD HDPE colorations with 1% TiO2 are heat stable to 230°C for 5 minutes (Industrial Organic Pigments, 3rd ed.).
Strong Tinctorial Strength
Only 0.21% pigment formulates a 1/3 SD HDPE coloration containing 1% TiO2, indicating good tinctorial strength in polyolefins (Industrial Organic Pigments, 3rd ed.).
Blue Scale 4-5 Lightfastness
1/1 SD letterpress proof prints equal step 4-5 on the Blue Scale, distinctly more lightfast than PR48:1 at step 3-4. In LDPE, PR48:2 outperforms PR48:1 by roughly 2.5 Blue Scale steps.
Solvent Fastness Close to Barium Lake
Fastness to organic solvents approaches that of the corresponding barium salt, supporting use in nitrocellulose-based packaging inks and solvent-borne coating systems.
Technical Specifications
| Property | Value |
|---|---|
| Color Index | Pigment Red 48:2 |
| C.I. Number | C.I. 15865:2 |
| Chemical Class | Monoazo lake (calcium salt, BONA) |
| CAS Number | 7023-61-2 |
| Molecular Formula | C18H11ClN2O6SCa |
| Appearance | Red powder |
| Shade | Bluish red (ruby) |
| Lightfastness | Blue Scale 4-5 (1/1 SD letterpress proof); TDS 6.0 |
| Heat Resistance | 260°C (TDS); 230°C (5 min, HDPE 1/3 SD) |
| Tinting Strength | 0.21% for 1/3 SD HDPE with 1% TiO2 |
| Density | 1.7 g/cm³ |
| Specific Surface Area | 58 m²/g |
| pH Value | 6.5-8.5 |
| Oil Absorption | 65 ml/100g |
| Migration Resistance | TDS 4.0; not entirely bleed resistant in plasticized PVC |
| Solvent Resistance | Good (close to barium lake) |
| Soap Fastness | Inferior to PR48:1 (barium lake) |
Applications Matrix
| Industry | Applications | Typical Loading | Notes |
|---|---|---|---|
| Printing Inks | Gravure packaging inks (standard process red); Nitrocellulose-based packaging inks; Three- and four-color magazine-cover printing; Letterpress inks | 12-22% on vehicle | Ruby shade suits packaging color targets; good organic solvent fastness for NC systems; resinated grades bronze less in print |
| Plastics | HDPE and LDPE coloring; Plasticized PVC (deep shades); PP spin dyeing (low-melt polymers only) | 0.21% for 1/3 SD HDPE with 1% TiO2 | 260°C TDS heat resistance covers polyolefin processing; more lightfast than PR48:1 in LDPE; use deep shades to ensure sufficient lightfastness |
| Industrial Paints | Oven-drying paints; Nitro paints; Emulsion paints | 5-12% on binder | Equal fastness to overcoating as the barium lake; increasing TiO2 in white reductions makes the pigment more light-sensitive |
Competitive Comparison
Positioning
Pigment Red 48:2 (HP RED 23124J) is a calcium-lake PR48:2 positioned for gravure and packaging ink formulators who need the GTA standard process red with 260°C heat stability and Blue Scale 4-5 lightfastness.
vs. DIC Corporation
DIC (Sun Chemical) covers the full PR48 range with global regulatory documentation and batch-to-batch consistency. HP RED 23124J delivers the same calcium-lake ruby shade for Asia-Pacific supply chains at a lower cost.
vs. Heubach
Heubach supplies azo red lakes with international certification. HP RED 23124J matches the standard calcium-lake process-red target with competitive China domestic pricing.
vs. Sudarshan
Sudarshan’s Sudaperm Red series includes PR48:2 calcium-lake grades with strong global distribution. HP RED 23124J matches the process-red color target with established supply-chain availability.
vs. PR48:1 (barium lake)
PR48:1 (barium salt) provides better soap and sterilization fastness but lower lightfastness (Blue Scale 3-4 vs 4-5) and a redder, less blue tone. PR48:2 calcium lake is preferred for gravure packaging inks and LDPE where lightfastness matters.
Frequently Asked Questions
What is Pigment Red 48:2 (HP RED 23124J) and its chemical composition?
Pigment Red 48:2 (C.I. 15865:2) is the calcium salt of a BONA monoazo red pigment, made by diazotizing 2B acid, coupling onto 2,3-acid, and laking with calcium. The calcium salt has the formula C18H11ClN2O6SCa and CAS number 7023-61-2. HP RED 23124J is the product grade.
What is the difference between Pigment Red 48:2 and Pigment Red 48:1?
PR48:2 is the calcium salt with bluish-red (ruby) shades; PR48:1 is the barium salt with light yellowish to medium red shades. PR48:2 is distinctly more lightfast (Blue Scale 4-5 vs 3-4) but inferior in soap and sterilization fastness.
Is HP RED 23124J suitable for gravure and offset printing inks?
Yes. PR48:2 was adopted by the Gravure Technical Association in 1986 as the standard process red for gravure packaging inks. It is also used in nitrocellulose-based packaging inks and three- and four-color magazine-cover printing.
What is the heat resistance and lightfastness of Pigment Red 48:2?
The HP RED 23124 TDS lists heat resistance of 260°C. 1/3 SD HDPE colorations with 1% TiO2 are heat stable to 230°C for 5 minutes. Lightfastness is Blue Scale step 4-5 in 1/1 SD letterpress proofs (Industrial Organic Pigments, 3rd ed.).
Can Pigment Red 48:2 be used in PVC and plastic coloring?
Yes. HP RED 23124J colors HDPE and LDPE with good tinctorial strength (0.21% for a 1/3 SD HDPE coloration with 1% TiO2). It is not entirely bleed resistant in plasticized PVC, so use deep shades there; for flexible PVC demanding low migration, the strontium salt PR48:3 is more bleed resistant.
Handling & Storage
Store Pigment Red 48:2 (HP RED 23124J) in a cool, dry location away from direct sunlight. Keep containers sealed to prevent moisture absorption. Under proper storage conditions (below 35°C, relative humidity < 70%), shelf life is minimum 3 years from manufacture date. Avoid contact with strong oxidizing agents.
Packaging
Available in 25 kg multi-ply paper bags with polyethylene liner, or 500 kg bulk bags upon request.
Related Products
- Pigment Red 48:1 (barium-lake PR48:1 yellowish-red pigment)
- Pigment Red 48:3 HP RED 2348 (strontium-lake PR48:3 red, 260°C heat resistance)
- Pigment Red family overview
- Pigment Red 48:2 HP RED 2347 (BBC-type toluidine red)
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